�Թ���

We are a synthetic chemistry group developing functional hybrid materials with atomic/molecular precision to address fundamental challenges in sustainable energy and human health-related applications. By enabling synthetic tunability, we will manipulate the material’s physical properties (e.g., length-scale, shape, dimension) to understand transport/transfer processes.

Specifically, we will focus on framework materials (e.g., metal-organic frameworks) and their heterostructures to explore and further to leverage the emergent optical and electrical properties for targeted applications, including electrochemical energy storage/conversion, sensing, and electronic/photonic devices. Our research will also involve methodology development and in-depth characterization to advance materials development.

• Lu, C.; Choi, J. Y.; Check, B.; Fang, X.; Spotts, S.; Nunez, D.; Park*, J. "Thiatruxene-Based Conductive MOF: Harnessing Sulfur Chemistry for Enhanced Proton Transport," J. Am. Chem. Soc. 2024, 146, 26313-26319.
• Fang, X.; Choi, J. Y.; Stodolka, M.; Pham, H. T. B.; Park*, J. "Advancing Electrically Conductive Metal–Organic Frameworks for Photocatalytic Energy Conversion." Acc. Chem. Res. 2024, 57, 2316–2325.
• Choi, J. Y.; Check, B.; Fang, X.; Blum, S.; Pham, H. T. B.; Tayman, K.; Park*, J. "Photocatalytic Hydrogen Peroxide Production through Functionalized Semiconductive Metal–Organic Frameworks," J. Am. Chem. Soc. 2024, 146, 1319–11327.
• Pham, H. T. B.; Choi, J. Y.; Fang, X.; Claman, A.; Huang, S.; Coates, S.; Wayment, L.; Zhang, W.; Park*, J. "Macrocyclic Ligand-Driven Ion Selectivity and High Surface Area in a 2D Conductive MOF," Chem 2024, 10, 199–210.
• Pham, H. T. B.; Choi, J. Y.; Stodolka, M.; Park*, J. "Maximizing the Potential of Electrically Conductive MOFs," Acc. Chem. Res. 2024, 57, 580–589.
• Choi, J. Y.; Stodolka, M.; Kim, N.; Pham, H. T. B.; Check, B.; Park*, J. "2D Conjugated Metal-Organic Framework as a Proton-Electron Dual Conductor," Chem 2023, 9, 143–153.
• Stodolka, M.; Choi, J. Y.; Fang, X.; Lu, C.; Pham, H. T. B.; Check, B.; Park*, J. "Electrosynthesis of a Nickel-Based Conductive Metal–Organic Framework with Controlled Morphology for Enhanced Capacitance," ACS Materials Lett. 2023, 49–55.
• Pham, H. T. B.#; Choi, J. Y.#; Huang, S.; Wang, X.; Claman, A.; Stodolka, M.; Yazdi, S.; Sharma, S.; Zhang, W.; Park*, J. "Imparting Functionality and Enhanced Surface Area to a 2D Electrically Conductive MOF via Macrocyclic Linker," J. Am. Chem. Soc. 2022, 144, 10615–10621.
• Choi, J. Y.#; Flood, J.#; Stodolka, M.; Pham, H. T. B.; Park*, J. "From 2D to 3D: Postsynthetic Pillar Insertion in Electrically Conductive MOF," ACS Nano 2022, 16, 3145–3151.
• Park, J.; Hinckley, A.; Huang, Z.; Feng, D.; Yakovenko, A.; Lee, M.; Chen, S.; Zou, X.; Bao, Z.* “Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework,” J. Am. Chem. Soc.2018, 140, 14533–14537
• Park, J.^†; Lee, M.^†; Feng, D.; Huang, Z.; Hinckley, A.; Yakovenko, A.; Zou, X.; Cui, Y.; Bao, Z.* “Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage,” J. Am. Chem. Soc.2018, 140, 10315–10323
• Park, J.^†; Xu, M.^†; Li, F.*; Zhou, H.-C.* “3D Long-range Triplet Migration in a Water-stable Metal–Organic Framework for Upconversion-based Ultralow-power in vivo �����������Բ�,” J. Am. Chem. Soc.2018, 140, 5493–5499
• Feng, D.^†; Lei, T.^†; Lukatskaya, M.^†; Park, J.; Huang, Z.; Lee, M.; Shaw, L.; Chen, S.; Yakovenko, A.A.; Kulkarni, A.; Xiao, J.; Fredrickson, K.; Tok, J.B.; Zou, X.; Cui, Y.; Bao, Z.* “Robust and Conductive Two-Dimensional Metal–Organic Frameworks with Exceptionally High Volumetric and Areal Capacitance,” Nat. Energy2018, 3, 30–36
• Park, J.; Jiang, Q.; Feng, D.; Mao, L.; Zhou, H.-C.* “Size-Controlled Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy,” J. Am. Chem. Soc.2016, 138, 3518–3525 (Highlighted in Hanbitsa as a rising researcher’s work in Korea)
• Park, J.; Jiang, Q.; Feng, D.; Zhou, H.-C.* “Controlled Generation of Singlet Oxygen in Living Cells by Tuning the Ratio of Photochromic Switch in Metal–Organic Frameworks,” Angew. Chem. Int. Ed.2016, 55, 7188–7193 (Featured as a “hot paper” and “inside cover”)
• Park, J.; Feng, D.; Zhou, H.-C.* “Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups,” J. Am. Chem. Soc.2015, 137, 11801–11809
• Park, J.; Feng, D.; Zhou, H.-C.* “Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores,” J. Am. Chem. Soc.2015, 137, 1663–1672
• Park, J.; Feng, D.; Yuan, S.; Zhou, H.-C.* “Photochromic Metal–Organic Frameworks: Reversible Control of Singlet Oxygen Generation,” Angew. Chem. Int. Ed.2015, 54, 430–435 (Featured as a “hot paper” and “frontispiece”; Highlighted in ChemistryViews and EFRC Newsletter, US Department of Energy)
• Lu, W.; Wei, Z.; Gu, Z.-Y.; Liu, T.-F.; Park, J.; Park, J.; Tian, J.; Zhang, M.; Zhang, Q.; Gentle III, T.; Bosch, M.; Zhou, H.-C.* “Tuning the Structure and Function of Metal–Organic Frameworks via Linker Design,” Chem. Soc. Rev.2014, 43, 5561–5593

(^† equal contribution; * corresponding author)